The dissociation constant of m-nitroanilinium ion in water-tetrahydrofuran solvents at 25 C
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Thermodynamics of Ion Association in the Saturated Solution of The Mixed Solvent (methanol+water) and Ion Pairing at 25.0°C
In this study, the ion association phenomenon in the saturated solution of KCl in the mixed solvent(methanol+water) was studied. The solubility of this compound in the mixed solvent (methanol+water by value percent of methanol = 60%), and in the presence of various molarities of NaNO3 wasdetermined by the solvent evaporation method at 25.0°C. The results enable us to estimate the valueof thermo...
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Using Solvent Evaporating and Atomic Emission Spectrophotometric methods, the solubility of Li2CO3 in waterat 25°C was determined. Comparing the value of thermodynamic solubility product constant, Ksp(th),(Ksp(tn) = exp(—AG.ss/RT)) of the mentioned salt to the value which is obtained from the observed solubility,shnolL-1 , and activity coefficients, f+ and f, which are estimated upon the extend...
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Using the mixed solvents, (water +ethanol + propanol), the solubility of CdF2 was determined byevaporating method at 25° C. The results showed that the sollbility, s, of CdF2 decreases bydecreasing the dielectric constant of the mixed solvent .Once the solubility of CdF2 was determined,the concentration solubility product, Ksp(c)=4s3, was calculated .Furthermore ,by estimating the meanactivity ...
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A spectrophotometric method was used to determine the acidity constant of 4'-carboxybenzo-24-crown-8 in 52% (w/w) ethanol-water mixture. The acid dissociation constant, Ka, was found to increase in the presence of Na+, K+, Rb+, Cs+ and Tl+ ions. The formation constants of the resulting 1:1 complexes between the carboxycrown a...
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ژورنال
عنوان ژورنال: Journal of Research of the National Bureau of Standards Section A: Physics and Chemistry
سال: 1970
ISSN: 0022-4332
DOI: 10.6028/jres.074a.039